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El-Asmy, Ahmed A.
- Zincon Polymer as a New Modifier for Selective Separation and Determination of Copper and Zinc from Synthetic, Water and Drug Samples
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Authors
Affiliations
1 Department of Chemistry, Faculty of Science, Mansoura University, Mansoura, EG
1 Department of Chemistry, Faculty of Science, Mansoura University, Mansoura, EG
Source
Indian Journal of Science and Technology, Vol 2, No 2 (2009), Pagination: 78-84Abstract
Chloromethyl polystyrene polymer (CMPSpolymer) has been modified with 2-carboxy-2-hydroxy- 5-sulfoformazyl benzene (Zincon) to be used as a new reagent for preconcentration of Cu(II) and Zn(II) ions. The modified polymer (Z-polymer) has been characterized by elemental analysis and IR spectra. Batch and column modes were operated. The newly designed polymer sorbs Cu(II) and Zn(II) quantitatively at pH 7 with flow rate of 5 ml min-1. The maximum sorption capacities for Cu(II) and Zn(II) ions were 1.26 and 1.04 mmol g-1. The preconcentration factors were 250 and 200 for Cu(II) and Zn(II) ions. The limit of detection was 4 and 5 ng ml-1 for Cu(II) and Zn(II) ions. The desorption was effective by using 5 ml of 0.1 mol l-1 HCl or HNO3 prior to detection using AAS. The modified polymer was highly ion-selective even in the presence of large concentration of electrolytes or organic media, with a preconcentration ability for Cu(II) and Zn(II) ions. The modified polymer was tested on its utility with synthetic, natural water and drug samples, showing RSD value of < 3% which reflects good accuracy and reproducibility.Keywords
Chloromethyl Polystyrene Polymer, Preconcentration of Cu(II) And Zn(II) IonsReferences
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- Synthesis, Characterization and Biological Activity of (E1, E2) N1,N2- Bis[1-(3,4-dihydroxyphenyl)ethylidene]oxalohydrazide Complexes: New Method for ZrO2+ Separation
Abstract Views :371 |
PDF Views:75
Authors
Affiliations
1 Chemistry Department, Faculty of Science, Mansoura University, Mansoura, EG
1 Chemistry Department, Faculty of Science, Mansoura University, Mansoura, EG
Source
Indian Journal of Science and Technology, Vol 2, No 3 (2009), Pagination: 9-15Abstract
The bond length, bond angle, HOMO, LUMO, dipole moment and charges on the atoms have been calculated to confirm the geometry of (E1, E2) N1,N2 - bis[1-(3,4-dihydroxyphenyl)ethylidene]oxalohydrazide, H6DPOH. The metal complexes of Cr3+, VO2+, ZrO2+, HfO2+, UO2 2+ and MoO2 2+ with H6DPOH have been prepared and characterized by partial elemental analysis, spectral studies (electronic; IR), thermal analysis and magnetic measurements. The data suggest the formation of [Cr(H4DPOH)(H2O)3Cl]H2O, [VO(H4DPOH)(H2O)2], [Hf(H4DPOH)(H2O)]H2O [UO2(H4DPOH)(H2O)2]2H2O [MoO2(H4DPOH)] and [(ZrO)2(H2DPOH)(C2H5OH)2]. H6DPOH behaves as a dibasic bidentate in all complexes except ZrO2+ which acts as a tetrabasic tetradentate for the two ZrO2+ ions. An octahedral geometry was proposed for the Cr3+, HfO2+, MoO2 2+and UO2 2+ complexes and square pyramid for VO2+. The Cr(III) or VO2+ complexes are necessary to degrade the DNA of Eukaryotic subject completely; the other complexes have little effect. H6DPOH was found applicable as a new reagent for the separation and preconcentration of ZrO2+ ions from different water samples using flotation technique with satisfactory results.Keywords
(E1, E2) N1,N2 - bis[1-(3,4-dihydroxyphenyl) ethylidene]oxalohydrazideReferences
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